Beijing FLUOBON Surfactant Institute

FLUOBON News

Monthly Focus!

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Aug 15, 2023, the "perfluorosulfonic acid resin-proton exchange membrane" project has received the "angel round" financing of 3 million CNY (which will account for 20% of the equity ratio in the newly established company). The investment is dedicated to the construction of a 100L (polymerized autoclave volume) perfluorosulfonic acid resin production line.
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January-June 2023, our lecture series titled "Metal cleaning agents" are published in the Chinese academic journal "Detergent & Cosmetics" (vol 46, No 1, 2, 3, 5 and 6).
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November-December 2022, our lecture series titled "Application of surfactants in the fields of energy and emulsified oil" are published in the Chinese academic journal "Detergent & Cosmetics" (vol 45, No 11 and No 12).

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Nov 2022, a new type of gas-leakage detecting agent is developed, which is applicable for low leaking pressure (as low as 300 Pa) in case of gas leaking slowly from pipelines or devices.

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Nov-Dec 2022, a new substitution product (name as 6411) for replacement of PFOS has been accepted and practically applied by many industrial customers.

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Nov 2022, our paper titled "Application of surfactants in the fields of energy and emulsified oil" is published in the Chinese academic journal "Detergent & Cosmetics" vol 45, No 11 (pp 67-70).

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Aug 2022, our paper titled "Application of surfactants in agriculture" is published in the Chinese academic journal "Detergent & Cosmetics" vol 45, No 8 (pp 55-59).

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Jun 2022, three Chinese patents on perfluorinated sulfonyl fluoride resin have been authorized.

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May-June, 2022, on the basis of successful laboratory-scale synthesis, small industrialized devices for the precursors and polymerization of perfluorosulfonate resin have been installed and are being improved.

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April, 2022, the oligomerization of hexafluoropropylene oxide is successfully achieved, as well as the separation of oligomers of different degrees of polymerization.

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March, 2022, the book "Practical Formulations of Surfactants" (in Chinese) by Jin-Xin Xiao and Zhen-Guo Zhao is published by Chemical Industry Press (Beijing).

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March 9th, 2021, the book "Practical Formulations of Surfactants" (in Chinese) by Jin-Xin Xiao and Zhen-Guo Zhao is officially submitted to Chemical Industry Press (Beijing).

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June 2, 2020, Dr. Hang XING publishes two Chinese patents (CN210643578U and CN210643927U).

May 2020, Three mini-reviews written by Dr. Jin-Xin Xiao are published in ¡°Almanac of China Surfactant Industry 2019¡± (published by ¡°China Research Institute of Daily Chemical Industry¡± and ¡°Productivity Promotion Center of Surfactants & Detergents¡±), the titles of which are ¡°Synthesis, performance and application of silicone surfactants¡±, ¡°Synthesis, performance and application of fluorinated surfactants¡± and ¡°Performance, application and production status of amino acid surfactants¡± (pp 17-27, 28-50, 51-58 in Chapter 1).

January 2020, Our paper titled ¡°Do we need to regard PFAS as evil? Our points of view¡± is published in Chinese academic journal ¡°China Surfactant Detergent & Cosmetics¡± (vol. 50, No. 1, 49-53).

Our paper titled " Improvement of Load Bearing Capacity of Nanoscale Superlow Friction by Synthesized Fluorinated Surfactant Micelles " is published in the academic journal " ACS Applied Nano Materials" (2018, 1, 2, 953¨C959. DOI: 10.1021/acsanm.7b00367).

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September 8-13th, 2019, Zi-Yi Wang participates in the 33rd ECIS Conference (Conference of The European Colloid and Interface Society) in Leuven, Belgium and presents a poster titled "The information told by a host molecule: Another proof for the selectivity of ¦Â-cyclodextrin in the mixtures of fluorinated and hydrogenated surfactants".

December 2019, Our paper titled "Fluorinated Surfactants and Fluorinated Polymer Materials (IV): Strategy for Solving PFOS Problems" is published in the academic journal "China Detergent & Cosmetics" vol 4, No 4. (pp 69-76).

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September 2019, Our paper titled "Fluorinated Surfactants and Fluorinated Polymer Materials (III): Personal Opinion on the Problems of PFOS" is published in the academic journal "China Detergent & Cosmetics" vol 4, No 3. (pp 54-62).

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June 2019, Our paper titled "Fluorinated surfactants and fluorinated polymer materials (II): Environmental and safety issues" is published in the academic journal "China Detergent & Cosmetics" vol 4, No 2. (pp 66-79).

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June 2019, Dr. Hang XING submits two Chinese patents.

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June 2019, Dr. Jin-Xin Xiao has been invited to write three chapters titled "amino acid surfactants", "silicone surfactants" and "fluorinated surfactants" in <Almanac of China Surfactant Industry (2019)>.


March 2019, Our paper titled "Fluorinated surfactants and fluorinated polymer materials (I): General review" is published in the academic journal "China Detergent & Cosmetics" vol 4, No 1 (pp 52-62).

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Aug 7th, 2018, The patent "Compounding of carbon-4 fluoride surfactant and application of compound system preparation method of carbon-4 fluoride surfactant to aqueous film forming foam extinguishing agent" (CN 105727825B) is authorized. It means that our C4-AFFF is ready to start a revolution in AFFF.

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Jul 22nd, 2018, our manuscript titled "The surface activity study of divalent salts of perfluorinated carboxylic acids (PFA) and the mixtures of PFA/trivalent metal salts" is published in Chinese academic journal "China Surfactant Detergent & Cosmetics" vol 48, No 7 (pp 363-370).

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Apr 24-26, 2018, our manuscripts are collected by "2018 International Conference on Surfactant & Detergent" (ICSD 2018) in Shanghai, China, the titles of which are "The surface activity study of divalent salts of perfluorinated carboxylic acids (PFA) and the mixtures of PFA/trivalent metal salts" and "Effects of polyoxyethylene ricinoleic acid methyl ester on the performance of liquid detergents". Tian-tian Zhang has participated in the conference in representative of all authors.

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Apr 20, 2018, our manuscript titled "Cationic-anionic fluorinated surfactant mixtures based on short fluorocarbon chains as potential aqueous film-forming foam" is accepted by the academic journal "Journal of Dispersion Science and Technology" (DOI: 10.1080/01932691.2018.1468262).
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Jan 16, 2018, Jin-Xin Xiao participates in "9th Zhejiang journal for overseas students: Symposium of Innovation and Entrepreneurship for Overseas Returnees". Jin-Xin Xiao presents a lecture titled "C4-fluorianted surfactants: a world-leading technology for high-efficiency fire-fighting agent".

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On the year of 2017-2018, our institute has cooperate with MT.Fire control, Yangtze Delta Region Institute of Tsinghua University, Zhejiang. Jin-Xin Xiao hold the post of director of "Centre of Smart Fire-fighting application". Our Aqueous film-forming foam (AFFF) has passed the 3C compulsory certification by Ministry of public security, and the performance of AFFF reaches the highest rating.

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Dec 2017, Our manuscript "Effects of Hydroxyl Groups in Organic Ammonium Counterions on the Properties of Fluorinated Surfactants" is published in academic journal "China Detergent & Cosmetics" (English edition) 2017, issue 4.

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Oct 2017, the book¡°Applied Technology of Surfactants¡±(in Chinese) by Jin-Xin Xiao and Zhen-Guo Zhao is published by Chemical Industry Press (Beijing).

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Oct 2017, Ningxia MT-FLUOBON Fine Chemical Ltd, co. has been founded.

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Sep 26, 2017, our manuscript titled "Properties of disodium salt of 1-sulfo-cyclohexanecarboxylic acid as a novel hydrotropic agent and its effects on room-temperature surface activity of perfluorooctanesulfonates with high Krafft points" has been published on the academic journal "Colloids and Surfaces A: Physicochemical and Engineering Aspects" 2017, volume 532, pages 144-149. DOI: 10.1016/j.colsurfa.2017.05.072

Sep 10-16, 2017, as a member of LONGDONG UNIVERSITY--FLUOBON Surfactant Engineering Technology Center, Ms. Zhang Tian-tian from College of Chemistry and Chemical Engineering in Longdong University joined the "Training Course for Basic knowledge of detergent and formulation technology" organized by "China Research Institute of Daily Chemical Industry" and "Science & Technology Committee of CCIA (China Cleaning Industry Association)".

Jul-Aug, 2017, the manuscript titled "An overview of novel surfactants for formulation of cosmetics with certain emphasis on acidic active substances" (in Chinese) has been published in the Chinese academic journal "Detergent & Cosmetics" on Issue 7 and Issue 8.

Apr-Jun, 2017, the manuscript titled "A review on natural surfactants" (in Chinese) has been published in the Chinese academic journal "Detergent & Cosmetics" on Issue 4, 5, and 6.

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Jan 2017, <Application Principle of Surfactants (2nd edn)> edited by Jin-Xin Xiao and Zhen-Guo Zhao, has achieved the Second Award of Books as Outstanding Publications in 2016 China petroleum and chemical industry.

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Jan 15-20, 2017, Zi-bing Xiao and Zi-han Xiao have participated in the 23rd winter fluorine conference (Clearwater Beach, Florida, USA) sponsored by ACS Division of Fluorine Chemistry. Our two papers titled "Surface activities of bivalent and trivalent salts of perfluorooctanoic acid and perfluorobutanoic acid in water and in organic liquids" and "Surface activity and interfacial activity of amine oxide type fluorinated surfactant and its mixture with anionic hydrocarbon surfactant in strong acidic solution" have been published on  page 25 and page 26.

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December, 2016, the serial lectures "Fluorinated surfactants and fluoropolymers" from section (I) to section (XII) have been published on the issue No 1-12 of <China Surfactant Detergent & Cosmetics> (2016) in Chinese.

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Sep 20, 2016, Our manuscript "Hydrotrope-Induced Enhancement of Room Temperature Surface Activity for High Krafft Point Fluorinated Surfactants" has been accepted by <Journal of Surfactants and Detergents>.

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Sep 20, 2016, the serial lectures "Fluorinated surfactants and fluoropolymers" from section (I) to section (IX) have been published on the issue No 1-9 of <China Surfactant Detergent & Cosmetics> (2016) in Chinese.

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Sep 10, 2016, Our paper titled "Solubilization effects of a novel hydrotropic agent on perfluorooctane sulfonate salts with high Krafft points" has been joined in the ECIS 2016-30th Conference of The European Colloid and Interface Society, in Rome, Italy. Zi-bing Xiao has participated in the conference in representative of all authors.

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May 16-19, 2016, our paper "Cationic-anionic fluorinated surfactant mixtures for replacement of PFOS products" has been joined in China POPs Forum 2016-- 11th POPs International Academci Conference in Xi'an, China.

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Apr. 27-29, 2016, Beijing FLUOBON Surfactant Institute, Civil Aviation Flight University of China, and LONGDONG UNIVERSITY¡ªFLUOBON Surfactant Engineering Technology Center participated in the "2016 International Conference on Surfactant & Detergent" (ICSD 2016) at Shanghai, China. We published 3 conference papers titled "Effects of hydroxyl groups in organic ammonium counterions on the properties of fluorinated surfactants", "Studies on the instability of equimolar cationic-anionic hydrogenated-fluorinated surfactant mixtures" and "Surface activities of perfluorooctanesulfonamines and perfluorooctanoate esters in organic solvents". On the conference, Prof. Bo-wan WU from LONGDONG UNIVERSITY¡ªFLUOBON Surfactant Engineering Technology Center made a report titled "Research and application of coal dust inhibitor of water mist type".

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Jan.-Apr. 2016, our serial lectures "Fluorinated surfactants and fluoropolymers" are published on the journal "China Surfactant Detergent £¦ Cosmetics", Part I to IV of which are titled "Performance, syntheses (production) and applications", "Environmental and safety issues", "My opinion on the problems of PFOS" and "Strategy for PFOS problems", respectively.

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November ~December 2015, our paper "Synthesis and performance of a cationic fluorinated surfactant" is published by the journal "China Surfactant Detergent & Cosmetics" 2015, 45(11): 611-615.

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November ~December 2015, our paper "Preparation of highly surface active lignosulfonates" is published by the journal "China Surfactant Detergent & Cosmetics" 2015, 45(10): 550-556.

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October 2015, ¡°Application Principle of Surfactants¡± (2nd edition) by Jin-Xin Xiao and Zhen-Guo Zhao is published by Chemical Industry Press, Beijing, 2015.

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September 2015, A novel product of Aqueous Film-Forming Foam (FLUOBON C4-AFFF) has been developed by our institute, whose fire-extinguishing time is qualified as IA grade. This product is the first case of AFFF based on short fluorocarbon chain (C4), containing no PFOS or PFOA etc. Comparing with C6-based AFFF, FLUOBON C4-AFFF truly corresponds with the spirit of Stockholm Convention, because according to literature report, fluorocarbon chain £ 4 would be neglectable in affecting environment or human body.

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Oct 30, 2014, our book ¡°Application Principle of Surfactants¡± (J.-X. Xiao and Z.-G. Zhao, Chemical Industry Press, Beijing, 2003, in Chinese) has been published three times (15000 copies sold) since 2003. Now the second edition is processed as requested by the publisher (Chemical Industry Press).

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Jun 23, 2014, Our paper "Effects of counterion structure on the surface activities of anionic fluorinated surfactants whose counterions are organic ammonium ions" is accepted by the journal "Colloids and Surfaces A: Physicochem. Eng. Aspects" (DOI: 10.1016/j.colsurfa.2014.06.041)

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Apr 2014, Our report paper is honored with "The most Innovation Award" on the "2014 International Conference on Surfactant & Detergent".

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Dec 1, 2013, our patent "A White Spirit Analyzer" (CN202494667U) is achieved the 3rd prize of "Science and Technology Achievement Award" in "the 3rd Summit of China Food Research & Industry".

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Sep 2013, the president of Beijing FLUOBON Surfactant Institute, Dr. Jin-Xin Xiao, is invited to write the review titled "fluorinated surfactant" published in <Almanac of China Surfactant Industry (2012)> (pp 28-46).

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May 18~20, 2013, our President of Beijing FLUOBON Surfactant Institute, Dr. Jin-Xin Xiao, returns to his old school-- Longdong University in Gansu Province. He accepted the request from the President of Longdong University for being part-time professor. During his visit, he made a report about surfactants for the students.

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May 19, 2013, College of Chemistry and Chemical Engineering of Longdong University collaborates with Beijing FLUOBON Surfactant Institute, and the Centre of Surfactant Engineering and Technology is founded, in which the members from FLUOBON (Jin-Xin Xiao and Hang Xing) hold the post of Deputy Director and Chief Engineer for the Centre.

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2012-2013, Our paper "Unusual location of the pyrene probe solubilized in the micellar solutions of tetraalkylammonium
perfluorooctanoates" is published by the international academic journal "Soft Matter", 2013, vol. 9, pp 1164¨C1171.

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2012-2013, Our paper "The role of NaSCN on the equimolar cationic-anionic surfactant mixtures: Evidence from NMR, surface
tension and dynamic light scattering" is published by the international academic journal "Colloids and Surfaces A:
Physicochem. Eng. Aspects", 2013, vol. 416, pp 16¨C22.

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Nov 8, 2012, Our paper "Unusual location of the pyrene probe solubilized in the micellar solutions of tetraalkylammonium
perfluorooctanoates" is accepted by the international academic journal "Soft Matter", DOI: 10.1039/C2SM27057A

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Nov, 2012, Our paper "The role of NaSCN on the equimolar cationic-anionic surfactant mixtures: Evidence from NMR, surface
tension and dynamic light scattering" is accepted by the international academic journal "Colloids and Surfaces A:
Physicochem. Eng. Aspects", DOI: 10.1016/j.colsurfa.2012.10.029
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Aug 13, 2012, Our developed "A White Spirit Analyzer" (CN202494667U) is patented.

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July, 2012, Welcome Dr. Zeng-Pei Dou to join us and lead our laboratory of organic synthesis.

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June, 2012, Congratulations to our members of FLUOBON, Zhi-Ming Gou and Hai-Qian Yu, receive their qualification for graduate student in universities.


June, 2012, the graduate students, Qiang Fan and Guo-Chao Lu, have finished all their research work in FLUOBON for master's degree, and return to Shaanxi University of Science and Technology.

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July, 2011, the research article titled "Anomalous effects of concentrated salts on the equimolarly mixed cationic-anionic surfactant mixtures" is published by the international journal "Soft Matter" 2011, 7, 5365-5372.

June, 2011, the research article titled "Dielectric Spectroscopy Investigation on the Interaction of Poly(diallyldimethylammoniumchloride) with Sodium Decylsulfate in Aqueous Solution" is published by the international journal "Journal of Physical Chemistry B" 2011, 115, 5766-5774.
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April 26, 2011, the research article titled "Anomalous effects of concentrated salts on the equimolarly mixed cationic-anionic surfactant mixtures" is published by the international journal "Soft Matter" on web (DOI:10.1039/C1SM05115F).

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April 21, 2011, the research article titled "Hydrogenated and Fluorinated Host-Guest Surfactants: Complexes of Cyclodextrins with Alkanes and Fluoroalkyl-Grafted Alkanes" is published by the famous international academic journal "Chemistry - A European Journal" 2011, 17(19), 5373-5380.

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April 21, 2011, the research article titled "Dielectric Spectroscopy Investigation on the Interaction of Poly(diallyldimethylammoniumchloride) with Sodium Decylsulfate in Aqueous Solution" is published by the international journal "Journal of Physical Chemistry B" on web (DOI: 10.1021/jp200486u).

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April 1, 2011, the research article titled "Dielectric Spectroscopy Investigation on the Interaction of Poly(diallyldimethylammoniumchloride) with Sodium Decylsulfate in Aqueous Solution" is accepted by the international journal "Journal of Physical Chemistry B".

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March 25, 2011, the research article titled "Anomalous effects of concentrated salts on the equimolarly mixed cationic-anionic surfactant mixtures" is accepted by the international journal "Soft Matter".

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March 25, 2011, the electronic version of research article titled "Hydrogenated and Fluorinated Host-Guest Surfactants: Complexes of Cyclodextrins with Alkanes and Fluoroalkyl-Grafted Alkanes" is published by the famous international academic journal "Chemistry - A European Journal" on web (DOI: 10.1002/chem.201003443).

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January 11, 2011, the research article titled "Participation of the Inclusion Complexes in the Surface Adsorbed Layer in the Mixtures of ¦Á-Cyclodextrin and Cationic-Anionic Hydrogenated and Fluorinated Surfactants: A Surface Tension Proof" is accepted by the international journal "Journal of Chemical & Engineering Data".

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January 4, 2011, the research article titled "Hydrogenated and Fluorinated Host-Guest Surfactants: Complexes of Cyclodextrins with Alkanes and Fluoroalkyl-Grafted Alkanes" is accepted by the famous international academic journal "Chemistry - A European Journal". We propose a concept of "Host-Guest Surfactant" and have successfully designed and synthesized the hydrogenated and fluorinated host-guest surfactants. The headgroup and the hydrophobic tail in this kind of surfactants are connected by supramolecular interactions rather than covalent bonds.

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October 12, 2010, the research article titled ¡°Effect of Headgroup Size on the Thermodynamic Properties of Micellization of Dodecyltrialkylammonium Bromides¡± is published on the international academic journal "Journal of Chemical & Engineering Data" on web, Article ASAP, DOI: 10.1021/je100598x.

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October, 2010, the research article titled ¡°Surface activity, wetting and foaming properties of trialkylammonium perfluorooctanoate¡± is published on the Chinese journal "China Surfactant Detergent & Cosmetics" issue 5, volume 40.

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September 20, 2010, the research article titled ¡°Interactions between Sodium Tetrafluoroethylene Pentamer-oxylbenzenesulfonate and Octyltriethylammonium Bromide¡± is published on the Chinese journal "Fine Chemicals" issue 9, volume 27.
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August 17, 2010,  the research article ¡°Surface activities of N-(3-dimethylamino) propyl perfluoroalkylsulfonamide hydrochloride¡± is published on the Chinese journal "China Surfactant Detergent & Cosmetics" issue 4, volume 40.
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May 13, 2010, the research article titled ¡°Thermodynamics of Aggregation of Ammonium/Tetraalkylammonium Perfluorooctanoates: Effect of Counterions¡± is published on the international academic journal ¡°Journal of Chemical & Engineering Data¡± Issue 5, volume 55.

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May 13, 2010, the research article titled ¡°A Study of the Behavior of a-Cyclodextrin with Single Solutions of Hydrogenated and Fluorinated Surfactants and Their Mixtures¡± is published on the international academic journal ¡°Journal of Chemical & Engineering Data¡± issue 5, volume 55.

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May 10, 2010, the branch lab of Beijing FLUOBON Surfactant Institute is founded: ¡°Laboratory of Enhanced Oil Recovery¡±.

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May 6, 2010, the research article titled ¡°Interactions between Sodium Perfluorobutane Sulfonate and Octyltriethylammonium Bromide¡± is published on the Chinese journal "Chinese Journal of Applied Chemistry" issue5, volume27.

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April 27, 2010, Chen Kai, who is from Shaanxi University of Science and Technology, is matriculated by Beijing Normal University as a graduate student for doctor's degree.

 

March 30, 2010, Chen Kai (from Shaanxi University of Science and Technology) has completed his research work of Master's dissertation in Beijing FLUOBON Surfactant Institute.

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March 24, 2010, based on the previous cooperation with "Lucky" company to develop the product FLUOBON-N101, we have researched on the fluorinated surfactants used in solvent of oil.

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March 15, 2010, with the cooperation with Prof. Aijin Huang (from Peking University), the production and development of GC column is under way.

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In January, 2010, the research article titled ¡°Study on properties of ethanol ammonium salts of perfluorooctanoate and perfluorooctylsulfonate surfactants¡± is published on the Chinese journal "Chemical Research and Application" issue 1, volume 22.

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In January, 2010, the research article titled ¡°Aggregation behavior of N-alkyl perfluorooctanesulfonamides in dimethyl sulfoxide solution¡± is published on the international academic journal ¡°Journal of Colloid and Interface Science¡± volume 342.

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